Citation

Oiye EN, Ribeiro MF, Okumura LL, Saczk AA, Ciancaglini P, de Oliveira MF. J. Forensic Sci. 2016; 61(4): 1122-1125.

Affiliation

Departamento de Química, FFCLRP, Universidade de São Paulo, 14040-901, Ribeirão Preto-SP, Brazil.

Copyright

(Copyright © 2016, American Society for Testing and Materials, Publisher John Wiley and Sons)

DOI

10.1111/1556-4029.13068

PMID

27364296

Abstract

The illegal use of formalin (commercial formaldehyde) in cosmetic products harms the health of individuals exposed to this substance. Over the last years, the commercial availability of these products, especially those containing irregular dosage of formaldehyde, has increased in Brazil. This work analyzes some products for hair treatment available in the Brazilian market and verifies their safety. The adopted analytical methodology involved sample derivatization with 2,4-dinitrophenylhydrazine, followed by high-performance liquid chromatography with ultraviolet detection (UV-VIS) at λ = 365 nm. The limit of quantification is 2.5 × 10(-3%) w/w, and the recovery tests were around 93%. Some of the samples contained high and illegal formaldehyde levels ranging from 9% to 19% (w/w) and others presented suitable concentrations of the analyte. On the basis of the results, this work discusses the efficiency and practicality of this analytical method for forensic purposes.

© 2016 American Academy of Forensic Sciences.

Language: en