
@article{ref1,
title="Towards Improved Reaction Runaway Studies: Kinetics of the N-Oxidation of 2-Methylpyridine Using Heat-flow Calorimetry",
journal="Process safety and environmental protection",
year="2002",
author="Papadaki, M. and Stoikou, V. and Mantzavinos, D. and Rodriguez Miranda, J.L.",
volume="80",
number="4",
pages="186-196",
abstract="Isothermal reaction calorimetry can be used for the development of theoretically sound kinetic models, even in the case of complex reactions. In this article, the reliability of a previously developed model is further tested. The N-oxidation of 2-methylpyridine modelled by Sempere et al. (Chem Engng Process 37: 33-46) in a 2 L Mettler-Toledo heat-flow calorimeter, in IQS, Spain, is being studied at Leeds University in a 1 L SIMULAR heat-flow calorimeter. The experimental results are compared with the model developed by Sempere et al. In principle, they corroborated the previous findings. Encountered deviations have been justified; further investigation is suggested.<p />",
language="",
issn="0957-5820",
doi="10.1205/095758202320439146",
url="http://dx.doi.org/10.1205/095758202320439146"
}