TY  - JOUR
PY  - 2002//
TI  - Towards Improved Reaction Runaway Studies: Kinetics of the N-Oxidation of 2-Methylpyridine Using Heat-flow Calorimetry
JO  - Process safety and environmental protection
A1  - Papadaki, M.
A1  - Stoikou, V.
A1  - Mantzavinos, D.
A1  - Rodriguez Miranda, J.L.
SP  - 186
EP  - 196
VL  - 80
IS  - 4
N2  - Isothermal reaction calorimetry can be used for the development of theoretically sound kinetic models, even in the case of complex reactions. In this article, the reliability of a previously developed model is further tested. The N-oxidation of 2-methylpyridine modelled by Sempere et al. (Chem Engng Process 37: 33-46) in a 2 L Mettler-Toledo heat-flow calorimeter, in IQS, Spain, is being studied at Leeds University in a 1 L SIMULAR heat-flow calorimeter. The experimental results are compared with the model developed by Sempere et al. In principle, they corroborated the previous findings. Encountered deviations have been justified; further investigation is suggested.<p /> 
LA  - 
SN  - 0957-5820
UR  - http://dx.doi.org/10.1205/095758202320439146
ID  - ref1
ER  -