TY - JOUR PY - 2006// TI - Flammability limits of multi-fluorinated compounds JO - Fire safety journal A1 - Kondo, Shigeo A1 - Urano, Y A1 - Takizawa, Kenji A1 - Takahashi, Akifumi A1 - Tokuhashi, Kazuaki A1 - Sekiya, Akira SP - 46 EP - 56 VL - 41 IS - 1 N2 - Flammability limits were measured for a number of multi-fluorinated compounds in a 12 L spherical glass vessel. It was found that the saturated multi-fluorinated compounds with F substitution rate larger than 0.625 are non-flammable. Those with F substitution rate of 0.625 may or may not be flammable depending on the molecular structure and the humidity condition. A numerical analysis was carried out on the observed values of flammability limits for some 120 compounds including the multi-fluorinated ones. For multi-fluorinated compounds with F substitution rate of 0.6 or less, the flammability limit values can be explained reasonably well by the analysis. It is to be noted, however, that even for the non-flammable multi-fluorinated compounds the numerical analysis tends to predict them to be flammable.
LA - SN - 0379-7112 UR - http://dx.doi.org/ ID - ref1 ER -