TY - JOUR PY - 2021// TI - Synthetic cannabinoids in e-liquids: a proton and fluorine NMR analysis from a conventional spectrometer to a compact one JO - Forensic science international A1 - Wu, Nao A1 - Danoun, Saïda A1 - Balayssac, Stéphane A1 - Malet-Martino, Myriam A1 - Lamoureux, Catherine A1 - Gilard, Véronique SP - 110813 EP - 110813 VL - 324 IS - N2 - The (1)H NMR profiles of 13 samples of e-liquids supplied by French customs were obtained with high-field and low-field NMR. The high-field (1)H NMR spectra allowed the detection of matrix signals, synthetic cannabinoids, and flavouring compounds. Quantitative results were obtained for the five synthetic cannabinoids detected: JWH-210, 5F-MDMB-PICA, 5F-ADB, 5F-AKB48, and ADB-FUBINACA. Conventional GC-MS analysis was used to confirm compound identification. Fluorine-19 NMR was proposed for the quantification of fluorinated synthetic cannabinoids and was successfully implemented on both 400 MHz and 60 MHz NMR spectrometers. This study based on few examples explored the potentiality of low-field NMR for quantitative and quantitative analysis of synthetic cannabinoids in e-liquids.

Language: en

LA - en SN - 0379-0738 UR - http://dx.doi.org/10.1016/j.forsciint.2021.110813 ID - ref1 ER -