TY - JOUR PY - 2006// TI - Alkyne metathesis: Toward simplicity and efficiency JO - Tetrahedron Letters A1 - Maraval, V. A1 - Lepetit, C. A1 - Caminade, A.-m. A1 - Majoral, J.-p. A1 - Chauvin, R. SP - 2155 EP - 2159 VL - 47 IS - 13 N2 - No catalyst pre-activation, no suicide alkyne, and no additive is required in an extremely simple procedure for the metathesis of alkyl-, alkenyl-, and aryl-propynes: just mix Mo(CO)6, p-chlorophenol, and the alkyne in 1,2-dichloroethane, heat at 85°C for 9-24 h, and the symmetrical alkyne is produced in ca. 95% yield. © 2006 Elsevier Ltd. All rights reserved.
Language: en
LA - en SN - 0040-4039 UR - http://dx.doi.org/10.1016/j.tetlet.2006.01.120 ID - ref1 ER -