Citation

Lekomtsev AS, Vekhter EP. J. Chromatogr. B Analyt. Technol. Biomed. Life Sci. 2004; 800(1-2): 291-294.

Affiliation

Chemistry Department, Research Institute of Hygiene, Toxicology and Occupational Pathology, Zemljachky st. 12, 400048 Volgograd, Russia. a-lek@vlink.ru

Copyright

(Copyright © 2004, Elsevier Publishing)

DOI

unavailable

PMID

14698268

Abstract

A method for calculation of the retention time of a compound in a temperature-programmed mode of GC analyses is proposed. The method is based on a detailed consideration of thermodynamics of chromatographic process and account of the actual state of a capillary column. The suggested approach permits estimation of probability of a poisonous agent in tests by means of information stored in the database, eliminating a need for reference standard of such an agent.

Language: en