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Journal Article

Citation

Gupta JP, Edwards DW. J. Hazard. Mater. 2003; 104(1-3): 15-30.

Affiliation

Department of Chemical Engineering, Loughborough University, LE11 3TU, Loughborough, UK. jpg@iitk.ac.in

Copyright

(Copyright © 2003, Elsevier Publishing)

DOI

unavailable

PMID

14602396

Abstract

Inherently safer design (ISD) concepts have been

with us for over two decades since their elaboration by Kletz [Chem. Ind. 9

(1978) 124]. Interest has really taken off globally since the early nineties

after several major mishaps occurred during the eighties (Bhopal, Mexico city,

Piper-alfa, Philips Petroleum, to name a few). Academic and industrial research

personnel have been actively involved into devising inherently safer ways of

production. The regulatory bodies have also shown deep interest since ISD makes

the production safer and hence their tasks easier. Research funding has also

been forthcoming for new developments as well as for demonstration projects.A

natural question that arises is as to how to measure ISD characteristics of a

process? Several researchers have worked on this [Trans. IChemE, Process Safety

Environ. Protect. B 71 (4) (1993) 252; Inherent safety in process plant design,

Ph.D. Thesis, VTT Publication Number 384, Helsinki University of Technology,

Espoo, Finland, 1999; Proceedings of the Mary Kay O'Connor Process Safety

Center Symposium, 2001, p. 509]. Many of the proposed methods are very elegant,

yet too involved for easy adoption by the industry which is scared of yet

another safety analysis regime. In a recent survey [Trans. IChemE, Process

Safety Environ. Prog. B 80 (2002) 115], companies desired a rather simple method

to measure ISD. Simplification is also an important characteristic of ISD. It is

therefore desirable to have a simple ISD measurement procedure.The ISD

measurement procedure proposed in this paper can be used to differentiate

between two or more processes for the same end product. The salient steps are:

Consider each of the important parameters affecting the safety (e.g.,

temperature, pressure, toxicity, flammability, etc.) and the range of possible

values these parameters can have for all the process routes under consideration

for an end product. Plot these values for each step in each process route and

compare. No addition of values for disparate hazards (temperature, pressure,

inventory, toxicity, flammability, etc.) is being suggested to derive an overall

ISD index value since that conceals the effects of different parameters.

Further, addition of numbers with different units ( degrees C for temperature,

atm/bar for pressure, t for inventory, etc.) is inappropriate in scientific

sense. The proposed approach has a major advantage of expanding consideration in

future to incorporate economic, regulatory, pollution control and worker health

aspects, as well as factors such as the experience one has or 'the comfort

level' one feels with each of the processes under consideration.

Additionally, it would also guide the designers and decision makers into

affecting specific changes in the processes to reduce the unsafe features.We

demonstrate our simple approach by using the example of six routes to make

methyl methacrylate as documented by Edwards and Lawrence [Trans. IChemE,

Process Safety Environ. Protect. B 71 (4) (1993) 252; Quantifying inherent

safety of chemical process routes, Ph.D. Thesis, Loughborough University,

Loughborough, UK, 1996] and show that the decision could well have been

different if addition of disparate hazards had not been done.

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