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Journal Article

Citation

Mirabelli MF, Chramow A, Cabral EC, Ifa DR. J. Mass Spectrom. 2013; 48(7): 774-778.

Affiliation

Department of Chemistry, York University, Toronto, ON, M3J1P3, Canada; Department of Chemistry, University of Calabria, Via P. Bucci, 87030, Arcavacata di Rende, Cosenza, Italy.

Copyright

(Copyright © 2013, John Wiley and Sons)

DOI

10.1002/jms.3205

PMID

23832933

Abstract

Desorption electrospray ionization mass spectrometry (DESI-MS) is employed in the forensic analysis of chemical components present in condoms and imaging of latent fingerprints as circumstantial evidence of sexual assault. Polymers such as nonoxynol-9, polyethylene glycol, and polydimethylsiloxane, as well as small molecules additives such as N-methylmorpholine, N-octylamine, N,N-dibutyl formamide, and isonox 132, commonly used in lubricated condom formulations, were successfully characterized by DESI. The results suggest that DESI-MS is useful for identification of this type of evidence, and it has advantages over conventional extractive techniques, in terms of speed of analysis and ease of use. Copyright © 2013 John Wiley & Sons, Ltd.


Language: en

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